Beilstein J. Org. Chem.2019,15, 194–209, doi:10.3762/bjoc.15.19
precatalysts can be attributed to electronic and steric effects associated with the adjacent bulky phenyl groups.
Keywords: Grubbs-typeprecatalyst; hemilabile; 1-octene metathesis; pyridinyl-alcoholato ligand; Introduction
The alkene metathesis reaction is now well established as a powerful synthetic tool
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Graphical Abstract
Figure 1:
Structures of Grubbs 1 (1) and 2 (2) precatalysts.